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Preheat
 oven to 325 degrees. Line standard muffin tins with paper liners. Sift 
together cake flour, baking powder, and salt. Heat milk and vanilla-bean
 pod and seeds in a small saucepan over medium heat just until bubbles 
appear around the edge. Remove from heat. Whisk in butter until melted, 
and let stand 15 minutes. Strain milk mixture through a fine sieve into a
 bowl, and discard vanilla-bean pod. 
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With
 an electric mixer on medium speed, whisk together whole eggs, yolks, 
and sugar. Set mixing bowl over a pan of simmering water, and whisk by 
hand until sugar is dissolved and mixture is warm, about 6 minutes. 
Remove bowl from heat. With an electric mixer on high speed, whisk until
 mixture is fluffy, pale yellow, and thick enough to hold a ribbon on 
the surface for several seconds when whisk is lifted. 
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Gently
 but thoroughly fold flour mixture into the egg mixture in three 
batches; stir 1/2 cup batter into the strained milk mixture to thicken, 
then fold milk mixture into the remaining batter until just combined. 
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Divide
 batter evenly among lined cups, filling each three-quarters full. Bake,
 rotating tins halfway through, until centers are completely set and 
edges are light golden brown, about 20 minutes. Transfer tins to wire 
racks to cool completely before removing cupcakes. 
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To
 finish, brush tops of cupcakes evenly with coffee-marsala syrup; repeat
 until all syrup has been used. Allow cupcakes to absorb liquid 30 
minutes. Dollop frosting onto cupcakes; refrigerate up to overnight in 
airtight containers. Dust generously with cocoa powder just before 
serving. 
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