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Preheat
oven to 325 degrees. Line standard muffin tins with paper liners. Sift
together cake flour, baking powder, and salt. Heat milk and vanilla-bean
pod and seeds in a small saucepan over medium heat just until bubbles
appear around the edge. Remove from heat. Whisk in butter until melted,
and let stand 15 minutes. Strain milk mixture through a fine sieve into a
bowl, and discard vanilla-bean pod.
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With
an electric mixer on medium speed, whisk together whole eggs, yolks,
and sugar. Set mixing bowl over a pan of simmering water, and whisk by
hand until sugar is dissolved and mixture is warm, about 6 minutes.
Remove bowl from heat. With an electric mixer on high speed, whisk until
mixture is fluffy, pale yellow, and thick enough to hold a ribbon on
the surface for several seconds when whisk is lifted.
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Gently
but thoroughly fold flour mixture into the egg mixture in three
batches; stir 1/2 cup batter into the strained milk mixture to thicken,
then fold milk mixture into the remaining batter until just combined.
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Divide
batter evenly among lined cups, filling each three-quarters full. Bake,
rotating tins halfway through, until centers are completely set and
edges are light golden brown, about 20 minutes. Transfer tins to wire
racks to cool completely before removing cupcakes.
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To
finish, brush tops of cupcakes evenly with coffee-marsala syrup; repeat
until all syrup has been used. Allow cupcakes to absorb liquid 30
minutes. Dollop frosting onto cupcakes; refrigerate up to overnight in
airtight containers. Dust generously with cocoa powder just before
serving.
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